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A New Route to α-Carbolines Based on 6π-Electrocyclization of Indole-3-alkenyl Oximes
[Image: see text] Indoles are converted into α-carbolines in four steps by acylation at C-3, Boc-protection, olefination of the resulting 3-indolyl aldehydes or ketones to give N-Boc-3-indolyl alkenyl oxime O-methyl ethers, which upon heating to 240 °C under microwave irradiation undergo loss of the...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2013
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3971735/ https://ncbi.nlm.nih.gov/pubmed/24280001 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol403191k |
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