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Salen Promoted Enantioselective Nazarov Cyclizations of Activated and Unactivated Dienones
[Image: see text] A novel class of chiral 5,5′-di(2,4,6-trialkyl)aryl salen-metal complexes have been developed and shown to catalyze highly enantioselective Nazarov cyclization reactions, giving rise to cyclopentenoids in 90:10–98:2 er. Significantly, the catalysts also promote, for the first time,...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2013
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3964813/ https://ncbi.nlm.nih.gov/pubmed/23506509 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja401908m |
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