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A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis
[Image: see text] A set of protocols for catalytic enantioselective allylic substitution (EAS) reactions that allow for additions of alkenyl units to readily accessible allylic electrophiles is disclosed. Transformations afford 1,4-dienes that contain a tertiary carbon stereogenic site and are promo...
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Main Authors: | , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
American Chemical Society
2014
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Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3954459/ https://ncbi.nlm.nih.gov/pubmed/24467274 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4126565 |
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