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π vs σ-Radical States of One-Electron Oxidized DNA/RNA Bases: A Density Functional Theory Study
As a result of their inherent planarity, DNA base radicals generated by one electron oxidation/reduction or bond cleavage form π- or σ-radicals. While most DNA base systems form π-radicals there are a number of nucleobase analogs such as one-electron oxidized 6-azauraci1, 6-azacytosine, and 2-thioth...
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| Главные авторы: | , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2013
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3946539/ https://ncbi.nlm.nih.gov/pubmed/24000793 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp407897n |
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