Synthesis and characterization of "face-to-face" porphyrins.

The syntheses of four binary porphyrins, two of which are constrained to a "face-to-face" conformation, and their Co2+ and Cu2+ derivatives are described. Electron spin resonance indicates that the intermetallic separation in the binuclear "face-to-face" porphyrins is about 6.5-6.8 A. Electronic spe...

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Pubblicato in:	Proc Natl Acad Sci U S A
Autori principali:	Collman, J P, Elliott, C M, Halbert, T R, Tovrog, B S
Natura:	Artigo
Lingua:	Inglês
Pubblicazione:	National Academy of Sciences 1977
Soggetti:	Research Article
Accesso online:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC393187/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/189304/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.74.1.18
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