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The Role of Methoxy Group in the Nazarov Cyclization of 1,5-bis-(2-Methoxyphenyl)-1,4-Pentadien-3-one in the Gas Phase and Condensed Phase
[Image: see text] ESI-protonated 1,5-bis-(2-methoxyphenyl)-1,4-pentadien-3-one (1) undergoes a gas-phase Nazarov cyclization and dissociates via expulsions of ketene and anisole. The dissociations of the [M+ D](+) ions are accompanied by limited HD scrambling that supports the proposed cyclization....
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3930160/ https://ncbi.nlm.nih.gov/pubmed/24415061 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s13361-013-0785-8 |
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