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Protonated N-Alkyl-2-nitroanilines Undergo Intramolecular Oxidation of the Alkyl Chain upon Collisional Activation

The collisional activation of protonated N-propyl-2-nitroaniline obtained by electrospray ionization shows two major competitive dissociation pathways: the elimination of the elements of propionic acid, [M + H – C(3)H(6)O(2)](+) to give an m/z 107 ion, and of the elements of ethanol, [M + H – C(2)H(...

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Pubblicato in:Int J Mass Spectrom
Autori principali: Paulose, Justin, Cyriac, June, Mathai, George, Giblin, Daryl, Gross, Michael L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2016
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6565437/
https://ncbi.nlm.nih.gov/pubmed/31198403
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ijms.2016.06.008
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