Metal-ligand Covalency of Iron Complexes from High-Resolution Resonant Inelastic X-ray Scattering

Data from Kα resonant inelastic X-ray scattering (RIXS) have been used to extract electronic structure information, i.e., the covalency of metal-ligand bonds, for four iron complexes using an experimentally based theoretical model. Kα RIXS involves resonant 1s → 3d excitation and detection of the 2p...

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Hlavní autoři: Lundberg, Marcus, Kroll, Thomas, DeBeer, Serena, Bergmann, Uwe, Wilson, Samuel A., Glatzel, Pieter, Nordlund, Dennis, Hedman, Britt, Hodgson, Keith O., Solomon, Edward I.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3920600/
https://ncbi.nlm.nih.gov/pubmed/24131028
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja408072q
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