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Stereodivergent Synthesis of Chiral Fullerenes by [3 + 2] Cycloadditions to C(60)

[Image: see text] A wide range of new dipoles and catalysts have been used in 1,3-dipolar cycloadditions of N-metalated azomethine ylides onto C(60) yielding a full stereodivergent synthesis of pyrrolidino[60]fullerenes with complete diastereoselectivities and very high enantioselectivities. The use...

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Detalhes bibliográficos
Main Authors: Maroto, Enrique E., Filippone, Salvatore, Suárez, Margarita, Martínez-Álvarez, Roberto, de Cózar, Abel, Cossío, Fernando P., Martín, Nazario
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2013
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3914395/
https://ncbi.nlm.nih.gov/pubmed/24359021
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja410408c
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