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Catalytic, Enantioselective, Intramolecular Carbosulfenylation of Olefins. Preparative and Stereochemical Aspects

The first catalytic, enantioselective, intramolecular carbosulfenylation of isolated alkenes with aromatic nucleophiles is described. The combination of N-phenylsulfenylphthalimide, a chiral selenophosphoramide derived from BINAM, and ethanesulfonic acid as a co-catalytic Brønsted acid induced an ef...

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Autori principali: Denmark, Scott E., Jaunet, Alex
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2013
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3913010/
https://ncbi.nlm.nih.gov/pubmed/24328051
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo4023765
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