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Chiral Cyclopropenyl Ketones— Reactive and Selective Diels-Alder Dienophiles

[Image: see text] The synthesis and Diels-Alder reactions of cyclopropenyl ketones are described. Cyclopropenyl ketones are highly reactive dienophiles that can engage a range of cyclic dienes and 2,3-dimethylbutadiene. The strategy of using cyclopropenyl ketones to facilitate Diels-Alder reactions...

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Bibliographic Details
Main Authors: Fisher, Laural A., Smith, Natalee J., Fox, Joseph M.
Format: Artigo
Language:Inglês
Published: 2013
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3908886/
https://ncbi.nlm.nih.gov/pubmed/23438063
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo302683t
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