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A Simple Method for the Electrophilic Cyanation of Secondary Amines
[Image: see text] Bleach oxidizes trimethylsilyl cyanide to generate an electrophilic cyanating reagent that readily reacts with an amine nucleophile. This oxidative N-cyanation reaction allows for the preparation of disubstituted cyanamides from amines without using highly toxic cyanogen halides.
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3907775/ https://ncbi.nlm.nih.gov/pubmed/24313859 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol403245r |
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