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Copper–sulfenate complex from oxidation of a cavity mutant of Pseudomonas aeruginosa azurin

Metal–sulfenate centers are known to play important roles in biology and yet only limited examples are known due to their instability and high reactivity. Herein we report a copper–sulfenate complex characterized in a protein environment, formed at the active site of a cavity mutant of an electron t...

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Detalhes bibliográficos
Main Authors: Sieracki, Nathan A., Tian, Shiliang, Hadt, Ryan G., Zhang, Jun-Long, Woertink, Julia S., Nilges, Mark J., Sun, Furong, Solomon, Edward I., Lu, Yi
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2014
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3903256/
https://ncbi.nlm.nih.gov/pubmed/24390543
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1316483111
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