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Copper–sulfenate complex from oxidation of a cavity mutant of Pseudomonas aeruginosa azurin
Metal–sulfenate centers are known to play important roles in biology and yet only limited examples are known due to their instability and high reactivity. Herein we report a copper–sulfenate complex characterized in a protein environment, formed at the active site of a cavity mutant of an electron t...
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Main Authors: | , , , , , , , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
National Academy of Sciences
2014
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3903256/ https://ncbi.nlm.nih.gov/pubmed/24390543 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1316483111 |
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