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Alternative Derivations of the Statistical Mechanical Distribution Laws

A new approach is presented for the derivation of statistical mechanical distribution laws. The derivations are accomplished by minimizing the Helmholtz free energy under constant temperature and volume, instead of maximizing the entropy under constant energy and volume. An alternative method involv...

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Detalles Bibliográficos
Publicado en:Proc Natl Acad Sci U S A
Autor principal: Wall, Frederick T.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 1971
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Acceso en línea:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC389279/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16578712/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.68.8.1720
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