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Alternative Derivations of the Statistical Mechanical Distribution Laws
A new approach is presented for the derivation of statistical mechanical distribution laws. The derivations are accomplished by minimizing the Helmholtz free energy under constant temperature and volume, instead of maximizing the entropy under constant energy and volume. An alternative method involv...
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
1971
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC389279/ https://ncbi.nlm.nih.gov/pubmed/16578712 |
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