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Copper-Mediated Radical Trifluoromethylation of Unsaturated Potassium Organotrifluoroborates

Copper-mediated trifluoromethylation of unsaturated organotrifluoroborates with the Langlois reagent (NaSO(2)CF(3)) and TBHP allows the introduction of trifluoromethyl groups into a variety of organic substructures. The reactions are easy to set up, the conditions are mild and general, and the proce...

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Autors principals: Presset, Marc, Oehlrich, Daniel, Rombouts, Frederik, Molander, Gary A.
Format: Artigo
Idioma:Inglês
Publicat: 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3886853/
https://ncbi.nlm.nih.gov/pubmed/24251623
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo4023233
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