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Ozonolysis of Unsaturated Organotrifluoroborates

Organotrifluoroborates are robust reagents capable of withstanding ozonolysis of remote alkenes, thus providing a new route to oxo-substituted organotrifluoroborates. The primary ozonides initially generated upon ozonolysis can be reduced with Zn/AcOH to afford the carbonyl compounds. Alternatively,...

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Detalhes bibliográficos
Main Authors: Molander, Gary A., Cooper, David J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2504467/
https://ncbi.nlm.nih.gov/pubmed/17408287
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo070130r
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