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Mononitrosyl Non-Heme Diiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products

Mononitrosyl diiron complexes having either an [Fe(II)·{FeNO}(7)] or an [Fe(III)·{FeNO}(7)] core formulation have been synthesized by methods that rely on redox state-induced differentiation of the diiron starting materials in an otherwise symmetrical dinucleating ligand environment. The synthesis,...

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Detalhes bibliográficos
Main Authors: Majumdar, Amit, Lippard, Stephen J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3885238/
https://ncbi.nlm.nih.gov/pubmed/24246021
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic4019508
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