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Arylation with Unsymmetrical Diaryliodonium Salts: A Chemoselectivity Study

Phenols, anilines, and malonates have been arylated under metal-free conditions with twelve aryl(phenyl)iodonium salts in a systematic chemoselectivity study. A new “anti-ortho effect” has been identified in the arylation of malonates. Several “dummy groups” have been found that give complete chemos...

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Detalhes bibliográficos
Main Authors: Malmgren, Joel, Santoro, Stefano, Jalalian, Nazli, Himo*, Fahmi, Olofsson, Berit
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3884774/
https://ncbi.nlm.nih.gov/pubmed/23788251
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201300860
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