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Competing Pathways in O‐Arylations with Diaryliodonium Salts: Mechanistic Insights
A mechanistic study of arylations of aliphatic alcohols and hydroxide with diaryliodonium salts, to give alkyl aryl ethers and diaryl ethers, has been performed using experimental techniques and DFT calculations. Aryne intermediates have been trapped, and additives to avoid by‐product formation orig...
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| Pubblicato in: | Chemistry |
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| Autori principali: | , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2017
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5639379/ https://ncbi.nlm.nih.gov/pubmed/28792102 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201703057 |
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