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Competing Pathways in O‐Arylations with Diaryliodonium Salts: Mechanistic Insights

A mechanistic study of arylations of aliphatic alcohols and hydroxide with diaryliodonium salts, to give alkyl aryl ethers and diaryl ethers, has been performed using experimental techniques and DFT calculations. Aryne intermediates have been trapped, and additives to avoid by‐product formation orig...

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Publicado en:Chemistry
Main Authors: Stridfeldt, Elin, Lindstedt, Erik, Reitti, Marcus, Blid, Jan, Norrby, Per‐Ola, Olofsson, Berit
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2017
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5639379/
https://ncbi.nlm.nih.gov/pubmed/28792102
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201703057
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