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Localized Molecular Orbital Description of Nitrogen Lone Pairs

The Boys localization procedure is applied to several molecules possessing nitrogen lone pairs. The Boys structures show a tendency for the N lone pairs to participate in bonding to nearby electron sinks. For example, the Boys structure for planar formamide has two equivalent τ-bond orbitals between...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Kleier, Daniel A., Hall, John H., Halgren, Thomas A., Lipscomb, William N.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 1974
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC388432/
https://ncbi.nlm.nih.gov/pubmed/16592157
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