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Reliability of the pair-defect-sum approximation for the strength of valence-bond orbitals

The pair-defect-sum approximation to the bond strength of a hybrid orbital (angular wave functions only) is compared to the rigorous value as a function of bond angle for seven types of bonding situations, with between three and eight bond directions equivalent by geometrical symmetry operations and...

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Detalhes bibliográficos
Main Authors: Pauling, Linus, Herman, Zelek S., Kamb, Barclay J.
Formato: Artigo
Idioma:Inglês
Publicado em: 1982
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC345969/
https://ncbi.nlm.nih.gov/pubmed/16593167
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