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Base mediated deprotection strategies for trifluoroethyl (TFE) ethers, a new alcohol protecting group

A trifluoroethyl (TFE) ether is specifically introduced as a protecting group in organic chemistry. Its first strategic application and removal in the total synthesis of vinigrol is discussed. Two lithium base mediated deprotection strategies for its removal are presented in this Letter. In one depr...

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Sonraí Bibleagrafaíochta
Main Authors: Yang, Qingliang, Njardarson, Jon T.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2013
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3878608/
https://ncbi.nlm.nih.gov/pubmed/24391289
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2013.10.097
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