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Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide

The trifluoromethylation of aryl iodides catalyzed by copper(I) salt with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide and Zn dust was accomplished. The catalytic reactions proceeded under mild reaction conditions, providing the corresponding aromatic trifluoromethylated...

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Main Authors: Nakamura, Yuzo, Fujiu, Motohiro, Murase, Tatsuya, Itoh, Yoshimitsu, Serizawa, Hiroki, Aikawa, Kohsuke, Mikami, Koichi
格式: Artigo
語言:Inglês
出版: Beilstein-Institut 2013
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC3869366/
https://ncbi.nlm.nih.gov/pubmed/24367406
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.277
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