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Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide

The trifluoromethylation of aryl iodides catalyzed by copper(I) salt with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide and Zn dust was accomplished. The catalytic reactions proceeded under mild reaction conditions, providing the corresponding aromatic trifluoromethylated...

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Autors principals: Nakamura, Yuzo, Fujiu, Motohiro, Murase, Tatsuya, Itoh, Yoshimitsu, Serizawa, Hiroki, Aikawa, Kohsuke, Mikami, Koichi
Format: Artigo
Idioma:Inglês
Publicat: Beilstein-Institut 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3869366/
https://ncbi.nlm.nih.gov/pubmed/24367406
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.277
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