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Epoxidation of (+/-)-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene during (bi)sulfite autoxidation: activation of a procarcinogen by a cocarcinogen.

The (bi)sulfite ion undergoes extensive autoxidation in neutral aqueous media with the formation of sulfur trioxide radical anion that is detected by ESR. The radical anion subsequently reacts with molecular oxygen to form a peroxyl radical. We find that when (+/-)-trans-7,8-dihydroxy-7,8-dihydroben...

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Udgivet i:Proc Natl Acad Sci U S A
Principais autores: Reed, G A, Curtis, J F, Mottley, C, Eling, T E, Mason, R P
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 1986
Fag:
Research Article
Online adgang:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC386746/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/3463979/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.83.19.7499
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