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Development of Zn-ProPhenol-Catalyzed Asymmetric Alkyne Addition: Synthesis of Chiral Propargylic Alcohols
The development of a general and practical zinc-catalyzed enantioselective alkyne addition methodology is reported. Commercially available ProPhenol ligand (1) has facilitated the addition of a wide range of zinc alkynylides to aryl, aliphatic and α,β-unsaturated aldehydes in high yield and enantios...
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| Autores principales: | , , , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2012
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3864595/ https://ncbi.nlm.nih.gov/pubmed/23097281 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201202085 |
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