A structure and reactivity analysis of monomeric Ni(II)–hydroxo complexes prepared from water()

The nickel(II) chemistry with the tridentate ligands bis[(N′-R-ureido)-N-ethyl]-N-methylamine (H(4)1(R), R = isopropyl, tert-butyl) is described. The Ni(II)–OH complexes, [Ni(II)H(2)1(R)(OH)](−) were generated using water as the source of the hydroxo ligand. These complexes are pseudo-square planar,...

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Hauptverfasser: Powell-Jia, Darla, Ziller, Joseph W., DiPasquale, Antonio G., Rheingold, Arnold L., Borovik, A. S.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2009
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3863642/
https://ncbi.nlm.nih.gov/pubmed/19352526
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b820209e
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