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Preparation of a Semiquinonate-Bridged Diiron(II) Complex and Elucidation of its Geometric and Electronic Structures

The synthesis and crystal structure of a diiron(II) complex containing a bridging semiquinonate radical are presented. The unique electronic structure of this S = 7/2 complex is examined with spectroscopic (absorption, EPR, resonance Raman) and computational methods.

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Detalhes bibliográficos
Main Authors: Baum, Amanda E., Lindeman, Sergey V., Fiedler, Adam T.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3860832/
https://ncbi.nlm.nih.gov/pubmed/23765069
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc42980f
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