Excited State Dynamics Can Be Used to Probe Donor-Acceptor Distances for H-Tunneling Reactions Catalyzed by Flavoproteins

In enzyme systems where fast motions are thought to contribute to H-transfer efficiency, the distance between hydrogen donor and acceptor is a very important factor. Sub-ångstrom changes in donor-acceptor distance can have a large effect on the rate of reaction, so a sensitive probe of these changes...

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Hlavní autoři: Hardman, Samantha J.O., Pudney, Christopher R., Hay, Sam, Scrutton, Nigel S.
Médium: Artigo
Jazyk:Inglês
Vydáno: The Biophysical Society 2013
Témata:
Proteins and Nucleic Acids
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3853081/
https://ncbi.nlm.nih.gov/pubmed/24314085
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bpj.2013.10.015
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