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Density matrix method for orbital localization

A method is presented for localizing molecular orbitals, based on diagonalizing subunits of the density matrix. First, nonbonding orbitals are found by diagonalizing the monatomic subunits; then, diatomic σ or π bonding and antibonding orbitals are obtained from the diatomic subunits for all bonded...

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Detalhes bibliográficos
Main Authors: Caldwell, Dennis, Redington, Patrick, Eyring, Henry
Formato: Artigo
Idioma:Inglês
Publicado em: 1979
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC383758/
https://ncbi.nlm.nih.gov/pubmed/16592668
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