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Density matrix method for orbital localization

A method is presented for localizing molecular orbitals, based on diagonalizing subunits of the density matrix. First, nonbonding orbitals are found by diagonalizing the monatomic subunits; then, diatomic σ or π bonding and antibonding orbitals are obtained from the diatomic subunits for all bonded...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Caldwell, Dennis, Redington, Patrick, Eyring, Henry
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 1979
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC383758/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592668/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.76.7.3042
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