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Metal cluster chemistry: Structure and stereochemistry in the polynuclear rhodium hydrides H(n)Rh(n)[P(OR)(3)](2n)

Crystallographic analyses of x-ray and neutron diffraction data have provided a definitive structural representation of {HRh[P(O-i-C(3)H(7))(3)](2)}(2) and {HRh[P(OCH(3))(3)](2)}(3). These polynuclear hydrides are generated from square planar H(2)Rh[P(OR)(3)](2) units by edge (hydrogen atom) sharing...

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Publicat a:Proc Natl Acad Sci U S A
Autors principals: Brown, R. K., Williams, J. M., Fredrich, M. F., Day, V. W., Sivak, A. J., Muetterties, E. L.
Format: Artigo
Idioma:Inglês
Publicat: National Academy of Sciences 1979
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Accés en línia:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC383543/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592645/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.76.5.2099
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