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Structure and chemistry of a metal cluster with a four-coordinate carbide carbon atom
Molecular metal clusters with carbide carbon atoms of low coordination number have been prepared; they are the anionic [HFe(4)C(CO)(12)(-)] and [Fe(4)C(CO)(12)(2-)] clusters. An x-ray crystallographic analysis of a tetraaminozinc salt of the latter has established a butterfly array of iron atoms wit...
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| Udgivet i: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
1981
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC319860/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592968/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.78.2.668 |
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