Structure and chemistry of a metal cluster with a four-coordinate carbide carbon atom

Molecular metal clusters with carbide carbon atoms of low coordination number have been prepared; they are the anionic [HFe(4)C(CO)(12)(-)] and [Fe(4)C(CO)(12)(2-)] clusters. An x-ray crystallographic analysis of a tetraaminozinc salt of the latter has established a butterfly array of iron atoms wit...

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Publicado en:	Proc Natl Acad Sci U S A
Autores principales:	Davis, Jimmy H., Beno, M. A., Williams, Jack M., Zimmie, JoAnn, Tachikawa, M., Muetterties, E. L.
Formato:	Artigo
Lenguaje:	Inglês
Publicado:	National Academy of Sciences 1981
Materias:	Physical Sciences: Chemistry
Acceso en línea:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC319860/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592968/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.78.2.668
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