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Guide to Enantioselective Dirhodium(II)-Catalyzed Cyclopropanation with Aryldiazoacetates

Catalytic enantioselective methods for the generation of cyclopropanes has been of longstanding pharmaceutical interest. Chiral dirhodium(II) catalysts prove to be an effective means for the generation of diverse cyclopropane libraries. Rh(2)(R-DOSP)(4) is generaally the most effective catalyst for...

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Autores principales: Chepiga, Kathryn M., Qin, Changming, Alford, Joshua S., Chennamadhavuni, Spandan, Gregg, Timothy M., Olson, Jeremy P., Davies, Huw M. L.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2013
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3834613/
https://ncbi.nlm.nih.gov/pubmed/24273349
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.04.075
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