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Pd-Catalyzed Semmler-Wolff Reactions for the Conversion of Substituted Cyclohexenone Oximes to Primary Anilines

Homogeneous Pd catalysts have been identified for the conversion of cyclohexenone and tetralone O-pivaloyl oximes to the corresponding primary anilines and 1-aminonaphthalenes. This method is inspired by the Semmler-Wolff reaction, a classic method that exhibits limited synthetic utility owing to it...

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Hlavní autoři: Hong, Wan Pyo, Iosub, Andrei V., Stahl, Shannon S.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3826266/
https://ncbi.nlm.nih.gov/pubmed/23987212
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4073172
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