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The Multistep, Eight-Electron Oxidation Catalyzed by the Cofactorless Oxidase, PqqC: Identification of Chemical Intermediates and their Dependence on Molecular Oxygen
The final step of the biosynthesis of the prokaryotic cofactor, PQQ, is catalyzed by PqqC, a cofactorless oxidase that brings about a ring closure and overall eight-electron oxidation of its substrate. Time-dependent acid quenching and subsequent HPLC separation and mass spectrometric analyses of re...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3825819/ https://ncbi.nlm.nih.gov/pubmed/23718207 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi4003315 |
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