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Pd-Catalyzed Alkynylation of 2-Chloroacetates and 2-Chloroacetamides with Potassium Alkynyltrifluoroborates

[Image: see text] The synthesis of β,γ-alkynyl esters and amides using air-stable potassium alkynyltrifluoroborates as nucleophilic partners in a mild Suzuki-Miyaura cross-coupling reaction has been achieved. Propargyl esters and amides were obtained in high yields using low catalyst loading, and th...

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Hlavní autoři: Molander, Gary A., Traister, Kaitlin M.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3820111/
https://ncbi.nlm.nih.gov/pubmed/24040828
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol402391z
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