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Pd-Catalyzed Cross-Coupling of Potassium Alkenyltrifluoroborates with 2-Chloroacetates and 2-Chloroacetamides

[Image: see text] A protocol for the stereocontrolled synthesis of (E)- and (Z)-β,γ-unsaturated esters and amides is reported. 2-Chloroacetates as well as secondary and tertiary 2-chloroacetamides were successfully employed as electrophiles in the Suzuki–Miyaura cross-coupling reaction with potassiu...

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Detalhes bibliográficos
Main Authors: Molander, Gary A., Barcellos, Thiago, Traister, Kaitlin M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3737580/
https://ncbi.nlm.nih.gov/pubmed/23767882
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol401377q
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