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A Critical Test of the “Tunneling and Coupled Motion” Concept in Enzymatic Alcohol Oxidation
The physical mechanism of C-H bond activation by enzymes is the subject of intense study and we have tested the predictions of two competing models for C-H activation in the context of alcohol dehydrogenase. The kinetic isotope effects (KIEs) in this enzyme have previously suggested a model of quant...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3818283/ https://ncbi.nlm.nih.gov/pubmed/24020836 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja405917m |
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