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Enantioselective Construction of α-Quaternary Cyclobutanones by Catalytic Asymmetric Allylic Alkylation
No Strain, No Gain! The first transition metal-catalyzed enantioselective α-alkylation of cyclobutanones is reported. This method employs palladium catalysis and an electron deficient PHOX type ligand to afford all–carbon α-quaternary cyclobutanones in good to excellent yields and enantioselectiviti...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2013
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3817853/ https://ncbi.nlm.nih.gov/pubmed/23686812 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201301815 |
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