Synthesis of enantiomerically pure (2S,3S)-5,5,5-trifluoroisoleucine and (2R,3S)-5,5,5-trifluoro-allo-isoleucine

A practical route for the stereoselective synthesis of (2S,3S)-5,5,5-trifluoroisoleucine (L-5-F(3)Ile) and (2R,3S)-5,5,5-trifluoro-allo-isoleucine (D-5-F(3)-allo-Ile) was developed. The hydrophobicity of L-5-F(3)Ile was examined and it was incorporated into a model peptide via solid phase peptide sy...

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Detalhes bibliográficos
Main Authors: Erdbrink, Holger, Nyakatura, Elisabeth K, Huhmann, Susanne, Gerling, Ulla I M, Lentz, Dieter, Koksch, Beate, Czekelius, Constantin
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2013
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Full Research Paper
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3817528/
https://ncbi.nlm.nih.gov/pubmed/24204411
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.236
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