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(Diisopinocampheyl)borane-Mediated Reductive Aldol Reactions: Highly Enantio and Diastereoselective Synthesis of Syn-Aldols from N-Acryloylmorpholine()
[Image: see text] An efficient and highly enantio- and diastereoselective synthesis of syn propionamide aldols is described. Formation of the Z-enolborinate via the hydroboration of 4-acryloylmorpholine with (diisopinocampheyl)borane followed by aldol reactions with representative achiral and chiral...
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| Главные авторы: | , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2013
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3813003/ https://ncbi.nlm.nih.gov/pubmed/23818095 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201302535 |
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