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Regioselective Ruthenium Catalyzed Hydrohydroxyalkylation of Dienes with 3-Hydroxy-2-oxindoles: Prenylation, Geranylation and Beyond

[Image: see text] The direct conversion of secondary to tertiary alcohols via ruthenium(0) catalyzed C-C coupling of substituted 3-hydroxy-2-oxindoles with various dienes is described. Coupling occurs in a completely regioselective manner in the absence of stoichiometric byproducts.

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Autors principals: Chen, Te-Yu, Krische, Michael J.
Format: Artigo
Idioma:Inglês
Publicat: 2013
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3800700/
https://ncbi.nlm.nih.gov/pubmed/23721207
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol401184k
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