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Stereoselective Total Synthesis of Hainanolidol and Harringtonolide via Oxidopyrylium-Based [5+2] Cycloaddition

The tetracyclic carbon skeleton of hainanolidol and harringtonolide was efficiently constructed by an intramolecular oxidopyrylium-based [5+2] cycloaddition. An anionic ring opening strategy was developed for the cleavage of the ether bridge in 8-oxabicyclo[3.2.1]octenes derived from the [5+2] cyclo...

תיאור מלא

שמור ב:
מידע ביבליוגרפי
Main Authors: Zhang, Min, Liu, Na, Tang, Weiping
פורמט: Artigo
שפה:Inglês
יצא לאור: 2013
נושאים:
גישה מקוונת:https://ncbi.nlm.nih.gov/pmc/articles/PMC3798225/
https://ncbi.nlm.nih.gov/pubmed/23930656
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja406255j
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