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Synthesis of Functionalized Cyclohexenone Core of Welwitindolinones via Rhodium- Catalyzed [5+1] Cycloaddition
[Image: see text] The cyclohexenone core of welwitindolinones was synthesized by a Rh(I)-catalyzed [5+1]-cycloaddition of an allenylcyclopropane with CO. A penta-substituted cyclopropane was prepared successfully by a Rh(II)-catalyzed intramolecular cyclopropanation of alkenes with chlorodiazoacetat...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3480994/ https://ncbi.nlm.nih.gov/pubmed/22783971 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol301614v |
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