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Ring closing and opening reactions leading to aza-polycyclic aromatic compounds

A series of functionalized aza-polycyclic aromatic compounds were prepared by a superacid-promoted ring closing and opening reaction cascade. A reaction mechanism is proposed, which involves reactive dicationic intermediates. A key step in the conversions involves ipso protonation of an aryl group a...

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Hlavní autoři: Kethe, Anila, Li, Ang, Klumpp, Douglas A.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3797622/
https://ncbi.nlm.nih.gov/pubmed/24143035
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2012.02.047
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