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Facile Synthesis of Unsymmetrical Acridines and Phenazines by a Rhodium(III)-Catalyzed Amination, Cyclization and Aromatization Cascade

New formal [3 + 3] annulations have been developed to obtain acridines and phenazines from aromatic azides and aromatic imines and azobenzenes, respectively. These transformations proceed through a cascade process of Rh(III)-catalyzed amination followed by intramolecular electrophilic aromatic subst...

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Main Authors: Lian, Yajing, Hummel, Joshua R., Bergman, Robert G., Ellman, Jonathan A.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2013
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3789141/
https://ncbi.nlm.nih.gov/pubmed/23957711
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja406131a
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