Asymmetric Formal Total Synthesis of the Stemofoline Alkaloids: The Evolution, Development and Application of a Catalytic Dipolar Cycloaddition Cascade

A formal synthesis of didehydrostemofoline and isodidehydrostemofoline has been accomplished by preparing an intermediate in the Overman synthesis of these alkaloids from commercially available 2-deoxy-D-ribose. The work presented in this account chronicles the evolution of our explorations to ident...

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Autores principales: Shanahan, Charles S., Fang, Chao, Paull, Daniel H., Martin, Stephen F.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2013
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3780458/
https://ncbi.nlm.nih.gov/pubmed/24072939
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.03.104
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